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Internal oxidation of Ag-VC composites
Škraba, Polona ...
The internal oxidation (IO) of Ag - VC composites containing 5 vol.% of carbide was examined at three oxidation temperatures (350, 400, 600 °C). Two mechanisms were observed due to the formation of ...double oxides with relativelylow melting points. At temperatures below the lowest eutectic point in-situ, or diffusion less IO, was observed with the formation and growth of oxide layers surrounding the initial carbide. At temperatures above the eutectic point IO resulted in the formation of liquid oxide pools, which grew in size and developed into a network of oxides within the metal matrix. The kinetics confirmed the presence of two distinct mechanisms
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