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Acid-catalyzed deuterium exchange in Hantzsch-type dihydropyridines
Kocjan, Darko
An interesting case of the acid-catalayzed deuterium exchange in methanol-d, was found for 4-phenyl-1,4-dihydropyridine derivatives that belong to the class of Ca-channel antagonists. Deuterium ...exchange of the C-alpha-methyl protons indicates formation of an enamine carbocation that can be described by three mesomeric models.
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